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Villarreal vs Napoli

Villarreal host Napoli in the Europe Champions League on Tuesday 13 October 2026, kick-off 20:00. Our model makes Villarreal favourites at 39%, with a 26% chance of a draw. In their last 1 meetings, Napoli won 0, Villarreal won 1 and 0 were drawn.

Europe Champions League Save
Villarreal
20:00
13 Oct
Napoli
Estadio de la Cerámica, Villarreal Referee: Daniel Siebert

Win probabilities

39%Villarreal 26%Draw 36%Napoli
Unlock every model market, including correct scores, half-time/full-time, team goals and corners, with Pro

From the OddAlerts probability model before kick-off.

Villarreal vs Napoli predictionPredicted scores and goal markets from our match simulation

Villarreal vs Napoli lineups

Predicted

Villarreal 4-4-2

  • 25 Péter Gulácsi
  • 15 Santiago Mouriño
  • 6 Pau Navarro
  • 12 Renato Veiga
  • 23 Sergi Cardona
  • 10 Alberto Moleiro
  • 18 Pape Gueye
  • 14 Santi Comesaña
  • 11 Ilias Akhomach
  • 22 Ayoze Pérez
  • 9 Georges Mikautadze

Napoli 3-4-2-1

  • 1 Alex Meret
  • 5 Benoît Badiashile
  • 13 Amir Rrahmani
  • 16 Rafa Marín
  • 37 Leonardo Spinazzola
  • 68 Stanislav Lobotka
  • 8 Scott McTominay
  • 22 Giovanni Di Lorenzo
  • 7 David Neres
  • 11 Kevin De Bruyne
  • 19 Rasmus Højlund

Villarreal vs Napoli team news

Villarreal are without 1 player and Napoli are without 6 players.

Villarreal 1 out

Tajon Buchanan Hamstring Injury · Missed 1 game · Out until 19 Oct 2026 Injured

Napoli 6 out

Alessandro Buongiorno Knee Surgery · Missed 12 games · Out until 1 Jan 2027 Injured
Frank Anguissa Adductor Pain · Missed 1 game · Out until 15 Oct 2026 Injured
Alisson Santos Hamstring Muscle Injury · Missed 3 games · Out until 15 Oct 2026 Injured
Costantino Favasuli Hamstring Strain · Missed 1 game · Out until 30 Nov 2026 Injured
Mathías Olivera Groin Injury · Missed 1 game · Out until 19 Oct 2026 Injured
Antonio Vergara Calf Injury · Missed 1 game · Out until 2 Nov 2026 Injured

Form

Villarreal L W W L L
Napoli W D W L L
VillarrealNapoli
0% Win rate 0%
2.00 Goals scored 0.00
3.00 Goals conceded 1.00
100% Both teams score 0%
100% Over 2.5 goals 0%
0% Clean sheets 0%
0% Scored first 0%
1.42 xG for 0.31
2.75 xG against 3.60
16.00 Match corners 6.00

From 1 and 1 matches.

Napoli vs Villarreal head to head

0 Napoli wins 0 draws 1 Villarreal wins
5.0 goals per game 100% both teams scored 100% over 2.5 goals
  1. 13 Oct 2026Champions League Villarreal 20:00 Napoli
  2. 17 Dec 2022Club Friendlies 3 Napoli 2–3 Villarreal